|
KMID : 1059519900340020171
|
|
Journal of the Korean Chemical Society
1990 Volume.34 No. 2 p.171 ~ p.178
|
|
|
Oxygen-atom Transfer of Bis(pyrroridinedithiocarbamato)dioxomolybdenum (Ⅵ) with Triphenylphosphine in 1,2-Dichloroethane
|
|
Kim Chang-Su
Song Se-June
|
|
|
Abstract
|
|
|
|
The rates of the reaction Of [MoO2(S2CNC4H8)2] with triphenylphosphine in 1,2-dichloroethane have been by the spectrophotometric method. The increase in absorbance at 514 nm has been interpreted as a result of production of [Mo2O3(S2CNC4H8)4] and the decrease in absorbance then corresponds to the reduction of [Mo2O3(S2CNC4H8)4]. The data suggest mechanisms involving the formation of μ-oxo dimer in the first stage and molybdenum(Ⅳ) in the second stage.
|
|
|
KEYWORD
|
|
|
|
|
|
FullTexts / Linksout information
|
|
|
|
|
|
Listed journal information
|
|
|